On the rear of the manifold are 2 brass blocks. One threads into the block and the other threads into that. The second one is the one the booster tube goes in. The one that threads into the manifold is painted blue with the engine, the other is added later so it is natural brass. The booster tube is also unpainted. Looks like this even though its a 428,
Cannister stand bolt is just the water neck bolt which has a recess in the head and yes it is painted.
PS: the exhaust manifolds should have overspray, I did not have it done at the point this picture was painted