Some restorers use silicon as a rust protectant...But keep silicon away from paint.
DIYers might use silicone. I doubt a pro restorer would.
Silicone has no effect on paint that is dry.
However, if you have this stuff in the shop it is possible to get it on an unpainted surface.
If you try to paint a surface that has even a minuscule amount of silicone on it you will get fisheyes in the paint.
I don't store silicone of any type in the main shop.