Alignment is in essence, setting up the Geometry of the components "combined". Moving one setting usually affects the other settings. Vintage Mustang Caster adjustments, can be altered much easier than most other vehicles, WITHOUT also affecting other critical settings such as camber but I doubt it wouldn't also change the toe setting somewhat. I wouldn't personally do a Caster angle change without also rechecking the camber and toe. (I do alignments at my day job).
I would ask what the reasoning is for your query.
I concur with Mr Gaines statements.